85426-43-3Relevant academic research and scientific papers
(Ethoxycarbonyliodomethyl)triphenylphosphonium Iodide: A Convenient Reagent for the Direct Synthesis of β-Substituted Propiolic Acids via the Corresponding Esters
Chenault, Jaques,Dupin, Jean-Francois E.
, p. 498 - 499 (2007/10/02)
Reaction between (ethoxycarbonyliodomethyl)triphenylphosphonium iodide, potassium carbonate, and various aromatic or aliphatic aldehydes in a liquid solid two phases system gives β-substituted propiolic esters.The corresponding acids are obtained in good yield by hydrolysis.
SYNTHESIS OF CYCLOHEXENYL-SUBSTITUTED ACRYLIC AND 3-HYDROXYPROPIONIC ACIDS AND THEIR HOMOLOGS
Gramenitskaya, V. N.,Inozemtseva, L. V.,Koz'mina, E. A.,Vul'fson, N. S.
, p. 2260 - 2267 (2007/10/02)
The corresponding 3-cyclohexenyl-substituted Z- and E-acrylic and 3-hydroxypropionic acids were synthesized from 3-cyclohexene-1-carbaldehyde and its methyl derivatives.Dehydration of the products under various conditions leads to the formation of the E isomers of the substituted acrylic acid and also isomerization, aromatization, and cyclization products.
