85433-11-0

Upstream product

• 6167-32-4 1,6:3,4-dianhydro-2-O-tosyl-D-galactose 
• 676-58-4 methylmagnesium chloride 
• 498-07-7 levoglucosan 

Downstream Products

• 110104-50-2 (1S,2S,3R,5R)-3-Benzyloxy-2-methyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 110104-55-7 (3R,4R,5S)-3-Benzyloxy-4,6-dimethyl-hept-6-ene-1,5-diol 
• 110104-51-3 ((2S,3S,4R)-4-Benzyloxy-6-methoxy-3-methyl-tetrahydro-pyran-2-yl)-methanol 
• 110104-53-5 (2S,3S,4R)-4-Benzyloxy-2-isopropenyl-6-methoxy-3-methyl-tetrahydro-pyran 
• 110104-48-8 (2S,3R,4S,5R)-4-Benzyloxy-5-[1,3]dithian-2-yl-3-methyl-hexane-1,2-diol 
• 110104-56-8 2,2-Dimethyl-propionic acid (3R,4R,5S)-3-benzyloxy-5-hydroxy-4,6-dimethyl-hept-6-enyl ester 
• 110104-57-9 2,2-Dimethyl-propionic acid (3R,4R,5S)-3-benzyloxy-5-hydroxy-4-methyl-5-((R)-2-methyl-oxiranyl)-pentyl ester 
• 110104-58-0 2,2-Dimethyl-propionic acid (3R,4R,5R,6S)-3-benzyloxy-5,7-dihydroxy-4,6-dimethyl-heptyl ester 
• 81076-89-3 1,6-anhydro-2,4-didesoxy-2,4-di-C-methyl-3-O-benzyl-β-D-glucopyranose 
• 81076-90-6 ((2S,3S,4S,5R)-4-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 131755-61-8 ((2S,3S,4R,5R,6S)-4-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 131755-62-9 ((2S,3S,4R,5R,6R)-4-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 105678-12-4 1,6-Anhydro-3-O-benzyl-2,4-dideoxy-2,4-di-C-methyl-β-D-allopyranose 

Relevant academic research and scientific papers

Some aspects of the alkylation of epoxides of 1,6-anhydropyranoses

The formation of C-alkyl derivatives from 1,6:2,3-dianhydro-manno-pyranose precursors has been examined.Regioselectivity at C2 is excellent when the C4 substituent is benzyloxy.However, with CH3, reaction at C2 and C3 occurs, although the ratio of product

THE OXIRANE RING OPENINGS OF THE DIANHYDRO SUGAR WITH HIGH REGIOSELETIVITY AND ITS USE IN PREPARATION OF TWO CHIRAL SEGMENTS OF 6-DEOXYERYTHRONOLIDE B

The oxirane ring of the dianhydro sugar 2 obtained from levoglucosan (1,6-anhydro-β-D-glucose) is opened regioselectively with organometallic carbon nucleophiles and its application to an asymmetric synthesis of the C1-C5 segment 9 t