85433-71-2Relevant articles and documents
Preparation and Cycloaddition Reactions of Some αβ-Unsaturated Dithioesters
Lawson, Kevin R.,Singleton, Alison,Whitham, Gordon H.
, p. 859 - 864 (2007/10/02)
β-Hydroxydithioesters (5) are obtained via trreatment of mixture of methyl dithioacetate and the appropriate carbonyl compound with sodium hydride in tetrahydrofuran. αβ-Unsaturated dithioesters (1) can be prepared from (5) by way of suitable elimination reactions.Cycloadducts are formed by the reaction of (1) with a number of dienophiles and one diene.