85437-89-4

Basic information

• Product Name: (Z)-3-(cyclohex-1-en-1-yl)acrylic Acid
• Synonyms: (Z)-3-(cyclohex-1-en-1-yl)acrylic Acid
• CAS NO: 85437-89-4
• Molecular Weight: 152.193
• Mol File: 85437-89-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-3-(cyclohex-1-en-1-yl)acrylic Acid(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-(cyclohex-1-en-1-yl)acrylic Acid(85437-89-4)
• EPA Substance Registry System: (Z)-3-(cyclohex-1-en-1-yl)acrylic Acid(85437-89-4)

Safety Data

• Hazardous Substances Data: 85437-89-4(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 74-86-2 acetylene 
• 27944-89-4 3-(cyclohex-1-en-1-yl)propiolic acid 

Relevant articles and documents

Semireduction of alkynoic acids via a transition metal-free α borylation-protodeborylation sequence

A method for the semi-reduction of alkynoic acids through an α-borylation and subsequent protodeborylation mechanism has been developed. The transition metal-free protocol is achieved through the activation of bis(pinacolato)diboron by an in situ generated carboxylate moiety yielding aryl acrylic acids. Our studies demonstrate an unprecedented dual role for the carboxylate anion that involves the activation of the diboron reagent and a directing effect in the α-borylation.

VINYL COPPER REAGENTS-16. SYNTHESIS OF CONJUGATED DIENES VIA THE ADDITION OF VINYL CUPRATES TO ACETYLENE

Some alkenyl cuprates add smoothly to acetylene yielding dienyl cuprates.