85464-55-7

Upstream product

• 60076-41-7 methyl 4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside 
• 3068-36-8 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl bromide 

Downstream Products

• 85464-56-8 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-{(2S,3R,4R,5S,6R)-3-benzyloxycarbonylamino-5-hydroxy-2-methoxy-6-[(4-methoxy-phenyl)-diphenyl-methoxymethyl]-tetrahydro-pyran-4-yloxy}-5-(2,4-dinitro-phenylamino)-tetrahydro-pyran-4-yl ester 
• 85464-57-9 Acetic acid (2R,3S,4R,5R,6S)-5-benzyloxycarbonylamino-4-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxycarbonylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-2-[(4-methoxy-phenyl)-diphenyl-methoxymethyl]-tetrahydro-pyran-3-yl ester 
• 85464-60-4 C₄₅H₅₁N₃O₁₆ 
• 85464-58-0 Acetic acid (3S,4R,5R,6S)-2-acetoxy-5-benzyloxycarbonylamino-4-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxycarbonylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-tetrahydro-pyran-3-yl ester 
• 85464-61-5 C₄₁H₄₇N₃O₁₃ 
• 85464-59-1 [(4aR,6S,7R,8R,8aS)-6-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-carbamic acid benzyl ester 
• 85502-93-8 [(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester 
• 85464-63-7 {(4aR,6S,7R,8R,8aS)-8-[(2S,3R,4R,5S,6R)-3-(2,4-Dinitro-phenylamino)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy]-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl}-carbamic acid benzyl ester 
• 85502-91-6 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-((2S,3R,4R,5S,6R)-3-benzyloxycarbonylamino-5-hydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-4-yloxy)-5-(2,4-dinitro-phenylamino)-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

A NEW SYNTHETIC APPROACH TO AMINOGLYCOSIDE ANTIBIOTICS BY USE OF OXIDATIVE DECARBOXYLATION AND REDUCTIVE DEACETOXYLATION AS KEY-REACTIONS

By use of a decarboxylation reaction with lead tetraacetate and a deacetoxylation reaction with sodium borohydride as key-reactions, paromamine (12) and tri-N-benzyloxycarbonylparomamine (12a) were synthesized from D-glucosamine.