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A NEW SYNTHETIC APPROACH TO AMINOGLYCOSIDE ANTIBIOTICS BY USE OF OXIDATIVE DECARBOXYLATION AND REDUCTIVE DEACETOXYLATION AS KEY-REACTIONS

DOI: 10.1016/S0040-4039(00)85695-6

Source and publish data:

Tetrahedron Letters p. 4717 - 4720 (1982)

Update date:2022-08-05

Topics:

Authors:

Yoshikawa, MasayukiYoshikawa, Masayuki

Ikeda, YoshiharuIkeda, Yoshiharu

Kayakiri, HiroshiKayakiri, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(00)85695-6

By use of a decarboxylation reaction with lead tetraacetate and a deacetoxylation reaction with sodium borohydride as key-reactions, paromamine (12) and tri-N-benzyloxycarbonylparomamine (12a) were synthesized from D-glucosamine.

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Full text of DOI:10.1016/S0040-4039(00)85695-6

Products guided by the article

Product name:Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-((4aR,6S,7R,8R,8aS)-7-benzyloxycarbonylamino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-5-(2,4-dinitro-phenylamino)-tetrahydro-pyran-4-yl ester

Cas No:85464-55-7

85464-55-7

R&D Labs maybe for 85464-55-7

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