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Triphenylphosphine-(8-ethylquinoline-α-C,N)nickel bromide is a complex organometallic compound, characterized by the presence of a nickel (Ni) center coordinated to a triphenylphosphine (PPh3) ligand and an 8-ethylquinoline ligand, which is bound through its α-carbon and nitrogen atoms. triphenylphosphine-(8-ethylquinoline-.alfa.-C,N)nickel bromide is a type of nickel complex that can be used as a catalyst in various chemical reactions, particularly in cross-coupling reactions, due to its ability to facilitate the formation of carbon-carbon bonds. The bromide (Br) counterion is associated with the complex, contributing to its overall charge balance. The structure and electronic properties of this complex make it a valuable tool in organic synthesis and homogeneous catalysis.

85465-11-8

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85465-11-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 85465-11-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,4,6 and 5 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 85465-11:
(7*8)+(6*5)+(5*4)+(4*6)+(3*5)+(2*1)+(1*1)=148
148 % 10 = 8
So 85465-11-8 is a valid CAS Registry Number.

85465-11-8Downstream Products

85465-11-8Relevant academic research and scientific papers

INTERACTION OF A ZEROVALENT NICKEL COMPLEX WITH ORGANOMERCURIALS

Isaeva, L. S.,Morozova, L. N.,Bashilov, V. V.,Petrovskii, P. V.,Sokolov, V. I.,Reutov, O. A.

, p. 253 - 256 (1983)

The oxidative addition of ArHgX (Ar=Ph, X=Cl; Ar=C6F5, X=Br) to the nickel complex (Ph3P)4Ni resulting in formation of ?-aryl derivatives of bivalent nickel, (Ph3P)2Ni(Ar)X, has been performed.It was found that the reaction between (Ph3P)4Ni and (C6F5)2Hg yields the bimetallic compound (Ph3P)2Ni(C6F5)HgC6F5.Similarly, the reaction between 3Hg and (Ph3P)4Ni gives (Ph3P)2NiHgGe(C6F5)3, containing a Ge-Ni-Hg-Ge chain.A five-membered metallocycle with a N -> Ni chelate bond was obtained from the reaction of (Ph3P)4Ni with 8-(α-bromomercuriethyl)quinoline.

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