Journal of Organometallic Chemistry p. 253 - 256 (1983)
Update date:2022-08-04
Topics:
Isaeva, L. S.
Morozova, L. N.
Bashilov, V. V.
Petrovskii, P. V.
Sokolov, V. I.
Reutov, O. A.
The oxidative addition of ArHgX (Ar=Ph, X=Cl; Ar=C6F5, X=Br) to the nickel complex (Ph3P)4Ni resulting in formation of ?-aryl derivatives of bivalent nickel, (Ph3P)2Ni(Ar)X, has been performed.It was found that the reaction between (Ph3P)4Ni and (C6F5)2Hg yields the bimetallic compound (Ph3P)2Ni(C6F5)HgC6F5.Similarly, the reaction between <(C6F5)3Ge>3Hg and (Ph3P)4Ni gives (Ph3P)2Nia Ge-Ni-Hg-Ge chain.A five-membered metallocycle with a N -> Ni chelate bond was obtained from the reaction of (Ph3P)4Ni with 8-(α-bromomercuriethyl)quinoline.
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Doi:10.1016/0022-328X(87)85187-2
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(1983)
