85473-93-4Relevant academic research and scientific papers
NOVAL SYNTHESIS OF 1,3,5-TRISELENANES FROM ALDEHYDES, AND NOVEL GENERATION OF SELENOALDEHYDES BY FRAGMENTATION OF 1,3,5-TRISELENANES
Takikawa, Yuji,Uwano, Akira,Watanabe, Hiroyuki,Asanuma, Masaki,Shimada, Kazuaki
, p. 6047 - 6050 (2007/10/02)
Reaction of aldehydes with (Me3Si)2Se in the presence of Lewis acid afforded 1,3,5-triselenanes via selenoaldehydes.Novel and convenient generation of selenoaldehydes was also achived by thermally- or Lewia acid-induced fragmentation of 1,3,5-triselenanes.
ZUR REINDARSTELLUNG VON 2.4.6-TRIPHENYL-1.3.5-TRISELENAN. (TRISELENOBENZALDEHYD)
Weissflog, Eckhard
, p. 241 - 244 (2007/10/02)
The reaction of benzaldehyde with hydrogenselenide in a saturated solution of hydrogen chloride in ethanol leads to the formation of trimeric selenobenzaldehyde.Extraction by trichloro methane leads to an 1:1-adduct, which is converted to the pure title c
