854823-95-3

Basic information

• Product Name: 4-chloro-p-menthane
• Synonyms: 4-chloro-p-menthane
• CAS NO: 854823-95-3
• Molecular Weight: 174.714
• Mol File: 854823-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-chloro-p-menthane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chloro-p-menthane(854823-95-3)
• EPA Substance Registry System: 4-chloro-p-menthane(854823-95-3)

Safety Data

• Hazardous Substances Data: 854823-95-3(Hazardous Substances Data)

Upstream product

• 500-00-5 3-p-menthene 
• 99-82-1 Menthane 
• 89-78-1 menthol 
• 470-65-5 p-menthane-4-ol 
• 7647-01-0 hydrogenchloride 
• 56-23-5 tetrachloromethane 
• 2216-51-5 (-)-menthol 
• 71-43-2 benzene 
• 10026-13-8 phosphorus pentachloride 
• 2216-52-6 Neomenthol 
• 490-99-3 DL-neomenthol 
• 1174658-50-4 C₂₂H₃₄O₇S 
• 1174658-51-5 C₁₉H₂₅NO₃S 
• 619-52-3 (1R)-menth-3-ene 

Downstream Products

• 470-65-5 p-menthane-4-ol 
• 500-00-5 3-p-menthene 
• 854823-91-9 2,4-dichloro-p-menthane 

Relevant articles and documents

Clarification of the stereochemical course of nucleophilic substitution of arylsulfonate-based nucleophile assisting leaving groups

(Chemical Equation Presented) Secondary alcohols modified as tosylates, PEG-sulfonates, or quisylates undergo inversion of configuration at the reacting center when treated with lithium halide in acetone at reflux, where the PEG-sulfonates and quisylates are substantially more reactive. In sterically hindered cases, elimination is a competing process. In contrast, when treated with TiCl4, simple secondary sulfonates give chloride products with partial inversion of configuration. Any observed retention of configuration in a given alkyl sulfonate substrate under these conditions is likely due to neighboring group participation or diastereoselective attack on a carbocation (or ion pair) rather than an SNi mechanism.