854932-99-3Relevant articles and documents
Preparation of optically active α-hydroxy oxime ether by diastereoselective imino 1,2-Wittig rearrangement of hydroximates and its application to synthesis of (+)-cytoxazone
Miyata, Okiko,Hashimoto, Jun,Iba, Ryuuichi,Naito, Takeaki
, p. 4015 - 4018 (2005)
The diastereoselective imino 1,2-Wittig rearrangement of hydroximates provides a novel method for the construction of optically active α-hydroxy oxime ethers. Upon treatment with LDA, allyl p-methoxyphenylhydroximate carrying a chiral auxiliary smoothly u