85526-22-3Relevant academic research and scientific papers
Monoozonolysis of 2,3-Dimethylbutadiene in Pentane and in Methanol
Griesbaum, Karl,Keul, Helmut,Agarwal, Sudhir,Zwick, Gerhard
, p. 409 - 415 (2007/10/02)
2,3-Dimethylbutadiene (1) was attacked predominantly at only one double bond by a deficient amount of ozone in pentane or in methanol.In pentane, an α,β-unsaturated ozonide (4) was formed, which was further converted into an α,β-dibromoozonide (2) and into an α,β-epoxyozonide (6), respectively.Ozonolysis of 1 in methanol afforded an α,β-unsaturated methoxy hydroperoxide (8) and formaldehyde as well as a joint coproduct (9) of the latter two fragments.
