855270-72-3

Upstream product

• 855270-80-3 4-pentenyl 2-amino-2-N-benxyloxycarbonyl-2-N,3-O-carbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 67-56-1 methanol 
• 855270-65-4 3-O-carbamoyl-4,6-O-isopropylidene-D-glucal 
• 821-09-0 n-Pent-4-enyl alcohol 

Downstream Products

• 855270-80-3 4-pentenyl 2-amino-2-N-benxyloxycarbonyl-2-N,3-O-carbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 855270-94-9 6-O-(3-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 
• 855271-08-8 1-adamantyl 3,4,6-tri-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-α-D-mannopyranoside 
• 855270-88-1 6-O-(2-amino-2-N-benzyloxycarbonyl-2-N,3-O-carbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 
• 855270-92-7 6-O-(2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 
• 855271-07-7 (-)-menthyl 3,4,6-tri-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-α-D-mannopyranoside 
• 855270-93-8 (-)-menthyl 3-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 855270-87-0 (-)-menthyl 2-amino-2-N-benzyloxycarbonyl-2-N,3-O-carbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 855271-05-5 4-pentenyl 3,4,6-tri-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-α-D-mannopyranoside 
• 855270-91-6 (-)-menthyl 2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 855271-01-1 4-pentenyl 3-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 
• 855271-03-3 4-pentenyl 3-O-acetyl-2-amino-2-N-benzyloxycarbonyl-2-deoxy-α-D-mannopyranoside 
• 855270-99-4 4-pentenyl 2-amino-2-N-benzyloxycarbonyl-2-deoxy-4,6-O-isopropylidene-α-D-mannopyranoside 

Relevant academic research and scientific papers

α-N-acetylmannosamine (ManNAc) synthesis via rhodium(II)-catalyzed oxidative cyclization of glucal 3-carbamates

Glucal 3-carbamates 1 and 7 underwent oxidative cyclization with iodobenzene diacetate or iodosobenzene in the presence of Rh2(OAc) 4, providing mannosamine 2-N,3-O-oxazolidinones. With iodosobenzene, incorporation of 4-penten-1-ol p

Protecting group and solvent control of stereo-and chemoselectivity in glucal 3-carbamate amidoglycosylation

In the Rh2(OAc)4-catalyzed amidoglycosylation of glucal 3-carbamates, anomeric stereoselectivity and the extent of competing C3-H oxidation depend on the 4O and 6O protecting groups. Acyclic protection permits high α-anomer selectivi