855306-29-5Relevant academic research and scientific papers
2-O-Propargyl ethers: Readily cleavable, minimally intrusive protecting groups for β-mannosyl donors
Crich, David,Jayalath, Prasanna
, p. 2277 - 2280 (2005)
(Chemical Equation Presented) The use of 2-O-propargyl ethers as protecting groups in 4,6-O-benzylidene-protected mannopyranosyl donors bearing either bulky silyl groups or glycosidic linkages on O3 overcomes the poor stereoselectivity achieved with the c
Enhanced diastereoselectivity in β-mannopyranosylation through the use of sterically minimal propargyl ether protecting groups
Crich, David,Jayalath, Prasanna,Hutton, Thomas K.
, p. 3064 - 3070 (2007/10/03)
2-O-Propargyl ethers are shown to be advantageous in the 4,6-O-benzylidene acetal directed β-mannosylation reaction. The effect is most pronounced when the O3 protecting group is a bulky silyl ether or a glycosidic bond; however, even with a 3-O-benzyl et
