855306-33-1

Upstream product

• 168138-26-9 phenyl 4,6-O-benzylidene-3-O-(4-methoxybenzyl)-1-thio-α-D-mannopyranoside 
• 159407-19-9 phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 951025-06-2 phenyl 4,6-O-benzylidene-3-O-(2-methylnaphthyl)-1-thio-α-D-mannopyranoside 
• 951025-07-3 phenyl 4,6-O-benzylidene-3-O-(2-naphthylmethyl)-2-O-(prop-2-ynyl)-1-thio-α-D-mannopyranoside 
• 855306-32-0 phenyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-p-methoxybenzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 855306-48-8 phenyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-(2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-1-thio-α-D-mannopyranoside 
• 951025-09-5 phenyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-(2-naphthylmethyl)-β-D-mannopyranosyl-(1->3)-4,6-O-benzylidene-2-O-(prop-2-ynyl)-1-thio-α-D-mannopyranoside 
• 855306-50-2 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->3)-4,6-O-benzylidene-2-O-(prop-2-ynyl)-β-D-mannopyranosyl-(1->3)-4,6-O-benzylidene-2-O-(prop-2-ynyl)-β-D-mannopyranoside 
• 855306-36-4 3β-cholestanyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-tert-butyldimethylsilyl-β-D-mannopyranoside 
• 855306-41-1 methyl 2,3,6-tri-O-benzyl-4-O-[4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-tert-butyldimethylsilyl-β-D-mannopyranosyl]-(1->4)-α-D-glucopyranoside 
• 855306-38-6 methyl 4-O-[4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-tert-butyldimethylsilyl-β-D-mannopyranosyl]-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 951025-13-1 methyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-(2-naphthylmethyl)-β-D-mannopyranosyl-(1->3)-4,6-O-benzylidene-2-O-(prop-2-ynyl)-β-D-mannopyranosyl-(1->3)-4,6-benzylidene-2-O-(prop-2-ynyl)-β-D-mannopyranoside 

Relevant academic research and scientific papers

Convergent synthesis of a β-(1→3)-mannohexaose

(Chemical Equation Presented) An as yet unknown β-(1→3)- mannohexaose has been synthesized by a block route involving the coupling of two trisaccharides. Comparison of three closely related attempted mannohexaose syntheses reinforces the influence of subt

Enhanced diastereoselectivity in β-mannopyranosylation through the use of sterically minimal propargyl ether protecting groups

2-O-Propargyl ethers are shown to be advantageous in the 4,6-O-benzylidene acetal directed β-mannosylation reaction. The effect is most pronounced when the O3 protecting group is a bulky silyl ether or a glycosidic bond; however, even with a 3-O-benzyl et

2-O-Propargyl ethers: Readily cleavable, minimally intrusive protecting groups for β-mannosyl donors

(Chemical Equation Presented) The use of 2-O-propargyl ethers as protecting groups in 4,6-O-benzylidene-protected mannopyranosyl donors bearing either bulky silyl groups or glycosidic linkages on O3 overcomes the poor stereoselectivity achieved with the c