855315-39-8

Upstream product

• 445483-95-4 (R)-((2S,5R)-5-Isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazin-2-yl)-phenyl-methanol 
• 445483-96-5 (2R,5S)-2-Isopropyl-3,6-dimethoxy-5-((R)-methoxy-phenyl-methyl)-2,5-dihydro-pyrazine 
• 855315-37-6 (2S,3R)-N-(tert-butyloxycarbonyl)-3-methoxyphenylalanine methyl ester 
• 100-52-7 benzaldehyde 

Downstream Products

• 855315-57-0 C₆₅H₇₉N₅O₁₁Si 
• 855315-48-9 C₅₃H₈₀N₆O₁₂ 
• 855315-59-2 Benzoic acid (2R,4S)-4-({(2S,3R)-2-amino-3-(tert-butyl-dimethyl-silanyloxy)-3-[1-(1,1-dimethyl-allyl)-1H-indol-3-yl]-propionyl}-methyl-amino)-4-[(S)-1-((1S,2R)-2-methoxy-1-methoxycarbonyl-2-phenyl-ethylcarbamoyl)-ethylcarbamoyl]-2-methyl-butyl ester 
• 855315-50-3 benzoic acid 4-{1-[2-methoxy-1-(1-{[1-(1-methoxycarbonyl-2,4-dimethyl-pent-3-enylcarbamoyl)-3-methyl-butyl]-methyl-carbamoyl}-2-methyl-propylcarbamoyl)-2-phenyl-ethylcarbamoyl]-ethylcarbamoyl}-2-methyl-4-methylamino-butyl ester 
• 855315-46-7 Benzoic acid (2R,4S)-4-(tert-butoxycarbonyl-methyl-amino)-4-[(S)-1-((1S,2R)-1-carboxy-2-methoxy-2-phenyl-ethylcarbamoyl)-ethylcarbamoyl]-2-methyl-butyl ester 
• 855315-44-5 (6S,9R,12S)-methyl 6-((R)-3-(benzoyloxy)-2-methylpropyl)-12-((R)-methoxy(phenyl)methyl)-2,2,5,9-tetramethyl-4,7,10-trioxo-3-oxa-5,8,11-triazatridecan-13-oate 
• 855315-41-2 (2S,3R)-2-((S)-2-tert-Butoxycarbonylamino-propionylamino)-3-methoxy-3-phenyl-propionic acid methyl ester 

Relevant academic research and scientific papers

Macrocyclization studies and total synthesis of cyclomarin C, an anti-inflammatory marine cyclopeptide

The studies on macrocyclization at possible sites toward the total synthesis of cyclomarin C are described. The results showed that both Trp and Phe derivatives involved in the target could not be the terminals of the final linear peptide precursors. Addi

Syntheses of four unusual amino acids, constituents of cyclomarin A

The stereoselective syntheses of four unusual amino acids, constituents of cyclomarin A, are described. The protected N-methylhydroxyleucine 2 was synthesized using Evans' asymmetric azide-transfer reaction. The unusual amino acid 3 was prepared via diastereoselective methylation of the L-aspartic acid derived lactone 13. The stereoselective formation of threo-β-methoxyphenylalanine 4 was performed via aldol reaction using Scho?llkopf's chiral glycine enolate. The synthesis of N-reverse prenylated tryptophane 5 was achieved by the AQN ligand-promoted Sharpless regioreversed asymmetric aminohydroxylation protocol.