855443-66-2Relevant academic research and scientific papers
Selective formation of non-conjugated olefins by samarium(II)-mediated elimination/isomerization of allylic benzoates
Schaefer, Sara L.,Roberts, Connor L.,Volz, Erasmus O.,Grasso, Monika R.,O'Neil, Gregory W.
, p. 6125 - 6128 (2013/10/22)
Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product
Chiral N-heterocyclic carbene-copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides: Steric and electronic effects on γ-selectivity
Selim, Khalid B.,Nakanishi, Hirotsugu,Matsumoto, Yasumasa,Yamamoto, Yasutomo,Yamada, Ken-Ichi,Tomioka, Kiyoshi
experimental part, p. 1398 - 1408 (2011/04/25)
Chiral N-heterocyclic carbene ligands were electronically and sterically tuned to improve γ-selectivity in copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides with several aryl Grignard reagents. High γ-selectivity was realized
