85545-27-3

Upstream product

• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37715-33-6 essigsaeure-<(E)-6,7-dihydroxy-3,7-dimethyl-2-octenyl>ester 
• 61302-42-9 (R,E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-ol 
• 171231-05-3 (R,E)-((5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-yl)oxy)trimethylsilane 

Downstream Products

• 122274-03-7 Toluene-4-sulfonic acid (1S,2R,4R)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl ester 
• 77704-42-8 (1S,2S,4R)-2-Benzenesulfonylmethyl-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]heptane 
• 124441-68-5 (2-Nitro-phenylsulfanylamino)-phenyl-acetic acid (1S,2R,4R)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl ester 
• 124441-86-7 Amino-phenyl-acetic acid (1R,2S,4S)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl ester 
• 124442-07-5 (S)-3-Amino-N-[phenyl-((1R,2S,4S)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethoxycarbonyl)-methyl]-succinamic acid 
• 124441-99-2 (S)-3-Benzyloxycarbonylamino-N-[phenyl-((1R,2S,4S)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethoxycarbonyl)-methyl]-succinamic acid benzyl ester 
• 122274-03-7 p-toluenesulfonylmethyl-2 trimethyl-1,3,3 oxa-7 bicyclo<2.2.1>heptane exo 

Relevant academic research and scientific papers

Efficient and highly selective cyclization induced by Lewis acid to generate 2-hydroxyl-α-cyclogeraniol

A cyclization reaction of the hydroxyl-protected geraniol epoxide induced by the different Lewis acids to generate 2-hydroxyl-α-cyclogeraniol has been explored. Compared with the previous methods, this method enhances the production and selectivity of this reaction without the consumption of a large amount of solvent. Also, the coordination of the metal with two oxygen atoms of hydroxyl groups might be crucial for the reaction is first addressed.