855855-00-4Relevant academic research and scientific papers
Carbazole-Based Tetrapodal Anchor Groups for Gold Surfaces: Synthesis and Conductance Properties
O'Driscoll, Luke J.,Wang, Xintai,Jay, Michael,Batsanov, Andrei S.,Sadeghi, Hatef,Lambert, Colin J.,Robinson, Benjamin J.,Bryce, Martin R.
, p. 882 - 889 (2019/12/24)
As the field of molecular-scale electronics matures and the prospect of devices incorporating molecular wires becomes more feasible, it is necessary to progress from the simple anchor groups used in fundamental conductance studies to more elaborate anchor
Synthesis of dihydroindolizines for potential photoinduced work function alteration
Bartucci, Matthew A.,Wierzbicki, Patrycja M.,Gwengo, Chengeto,Shajan, Sunny,Hussain, Syed H.,Ciszek, Jacob W.
, p. 6839 - 6842 (2011/03/18)
Seeking to immobilize photochromophores on metallic surfaces, we have synthesized four molecules which contain both a photoresponsive dihydroindolizine (DHI) core and a sulfur containing moiety, which allow for their assembly onto gold substrates. Sonogashira, Suzuki, or Ullmann couplings are employed to generate pyridines with pendant thioacetates (or disulfides). The pyridines are condensed with spiro[2-cyclopropene-1, 9′-[9H]fluorene]- 2, 3-dimethyl ester affording the targeted DHIs.
