85598-14-7

Upstream product

• 85598-13-6 1-bromo-4-methoxy-2-methyl-3-nitro-benzene 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 
• 85598-12-5 4-bromo-3-methyl-2-nitro-phenol 
• 4920-77-8 3-methyl-2-nitrophenol 
• 544-92-3 copper(I) cyanide 

Downstream Products

• 85628-22-4 N,N-Dimethyl-2-(2-nitro-3-methoxy-6-cyanophenyl)ethenamine 
• 85598-20-5 1-(p-Toluenesulfonyl)-4-methoxy-4-indoleacetonitrile 
• 85598-17-0 N-(p-Toluenesulfonyl)-4-formyl-7-methoxyindole 
• 85598-18-1 N-(p-Toluenesulfonyl)-4-hydroxymethyl-7-methoxyindole 
• 85598-19-2 N-(p-Toluenesulfonyl)-4-chloromethyl-7-methoxyindole 

Relevant academic research and scientific papers

A Homogeneous Method for the Conveniently Scalable Palladium- and Nickel-Catalyzed Cyanation of Aryl Halides

Homogeneous conditions for the palladium-catalyzed cyanation of aryl halides were developed. This new system features a broad scope of aryl chlorides and bromides, uses 2-propanol or 1-butanol as solvent, and is readily scalable. The same conditions can also provide simple benzonitriles using the recently developed (TMEDA)NiCl(o-tolyl) precatalyst in conjunction with 1,1′-bis(diphenylphosphino)ferrocene (dppf) as a ligand.