856016-97-2Relevant academic research and scientific papers
Convergent and diastereoselective synthesis of the polycyclic pyran core of saudin
Tambar, Uttam K.,Kano, Taichi,Zepernick, John F.,Stoltz, Brian M.
, p. 8357 - 8364 (2007/10/03)
The natural product saudin was found to induce hypoglycemia in mice and, therefore, could be an appealing lead structure for the development of new agents to treat diabetes. A diastereoselective tandem Stilleoxa- electrocyclization reaction has been devel
Progress toward the total synthesis of saudin: Development of a tandem Stille-oxa-electrocyclization reaction
Tambar, Uttam K.,Kano, Taichi,Stoltz, Brian M.
, p. 2413 - 2416 (2007/10/03)
(Chemical Equation Presented) A diastereoselective tandem Stille-oxa-electrocyclization reaction provides access to the core of the diterpenoid natural product saudin. Additionally, this new reaction sequence was extended to the convergent preparation of
