85615-58-3Relevant academic research and scientific papers
"Syn effect" in nucleophilic addition of amines to 1,3-dienyl sulfone and ethyl (E)-2,4-pentadienoate
Yamazaki, Masao,Guha, Samar Kumar,Ukaji, Yutaka,Inomata, Katsuhiko
experimental part, p. 740 - 753 (2009/04/10)
The stereochemistry of nucleophilic addition of amines to (E)-l-tosyl-l,3-butadiene was investigated. The Z/E ratios of the resulting allylic sulfones varied with amines, solvents, temperature, and concentration. When diethylamine was reacted in low conce
Diazo reactions with unsaturated compounds: XI. Reactions of benzene-, p-methylbenzene-, and p-methoxybenzenesulfonyl-1,3-butadienes with arenediazonium chlorides and 1-aryl-3,3-dimethyl-1-triazenes
Smalius,Naidan
, p. 1295 - 1298 (2008/02/04)
1-(p-Methylbenzene)-and 1-(p-methoxybenzenesulfonyl)-1,3-butadienes in aqueous acetone in the presence of copper(I) or copper(II) chlorides react with arenediazonium chlorides and 1-aryl-3,3-dimethyl-1-triazenes to form 1-(p-methylbenzene)-and 1-(p-methox
Synthesis of Allyl and Dienyl Sulphones via Iodosulphonylation of Conjugated Dienes
Barluenga, Jose,Martinez-Gallo, Jose M.,Najera, Carmen,Fananas, Francisco J.,Yus, Miguel
, p. 2605 - 2610 (2007/10/02)
The iodosulphonylation of conjugated dienes with sodium or mercury(II) toluene-p-sulphinate and iodine yields δ-iodoalkenyl sulphones stereoselectively.These compounds undergo stereospecific dehydrohalogenation to afford dienyl sulphones and nucleophilic
