856163-03-6Relevant articles and documents
Cationic ruthenium complexes based on planar polypyridyl ligand 2,4,6-tris (2-pyridyl)-1,3,5-triazine
Sharma, Sanjeev,Trivedi, Manoj,Chandra, Manish,Pandey, Daya Shankar
, p. 2573 - 2577 (2007/10/03)
New cationic complexes [Ru(κ3-tptz){(p-FC 6H4)3P}2Cl]BF4, [Ru(κ3-tptz){(p-CH3C6H4) 3P}2Cl]BF4,[Ru(κ3-tptz){(p- ClC6H4)3P}2 Cl]BF4, [Ru(κ3-tptz){(p-CH3OC6H4) 3P}2Cl]BF4, and [Ru(κ3-tptz) {p-(CH3)2NC6H4)3P} 2Cl]BF4 containing both group 15 donor and a planar polypyridyl ligand are prepared by reaction of RuCl3.xH2O with an excess amount of phosphines and 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) in methanol under refluxing conditions. The complexes have been characterized by elemental analyses and spectral techniques, viz., IR, 1H NMR, 31P NMR, FAB-MS and electronic spectral studies.