85620-85-5

Usage

InChI:InChI=1/C9H15NO2/c1-10(2)9(11)6-8-4-3-5-12-7-8/h3-4,8H,5-7H2,1-2H3/t8-/m0/s1

Upstream product

• 32742-34-0 1,5-Anhydro-D-arabinitol 
• 62445-02-7 2,3,4-tri-O-acetyl-1,5-anhydro-D-arabinitol 
• 3068-29-9 2,3,4-tri-O-acetyl-β-D-arabinosyl bromide 
• 50-69-1 D-Arabinose 
• 528869-25-2 (3S,4R,5R)-2-Bromo-tetrahydro-pyran-3,4,5-triol 
• 85620-83-3 (3aR,7R,7aS)-2-Ethoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 18871-66-4 N,N-dimethylacetamide dimethyl acetal 
• 85620-84-4 1,5-anhydro-2,3-dideoxy-D-glycero-pent-2-enitol 

Downstream Products

• 87614-56-0 5S-iodo-1S,6S-3,7-dioxabicyclo<4,3,0>nonan-8-one 
• 75452-42-5 C₃₂H₄₄O₅Si 
• 12650-69-0 mupirocin 
• 71980-98-8 pseudomonic acid C 
• 87678-99-7 1-{(2S,3R,4R,5S)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3,4-dihydroxy-tetrahydro-pyran-2-yl}-propan-2-one 
• 87678-98-6 1-{(2S,5R)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5,6-dihydro-2H-pyran-2-yl}-propan-2-one 
• 87614-61-7 C₄₀H₄₄O₇Si 
• 87641-25-6 C₃₆H₅₀O₆Si 
• 87614-60-6 2-{(2S,5R)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5,6-dihydro-2H-pyran-2-yl}-N,N-dimethyl-acetamide 
• 75452-45-8 C₂₅H₄₀O₆ 
• 87614-59-3 (3S,4S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3,4-dihydro-2H-pyran-4-ol 
• 87614-58-2 (3S,4S)-3-(2-Hydroxy-ethyl)-3,4-dihydro-2H-pyran-4-ol 
• 85620-93-5 N,N-Dimethyl-2-((2S,5R)-5-phenylcarbamoylmethyl-5,6-dihydro-2H-pyran-2-yl)-acetamide 
• 85620-92-4 2-((3S,4S)-4-Hydroxy-3,4-dihydro-2H-pyran-3-yl)-N-phenyl-acetamide 

Relevant academic research and scientific papers

ENANTIOSPECIFIC TOTAL SYNTHESIS OF PSEUDOMONIC ACIDS FROM ARABINOSE

The enantiospecific synthesis of pseudomonic acids from arabinose is described.

ENANTIOSPECIFIC SYNTHESES OF INTERMEDIATES IN THE TOTAL SYNTHESIS OF PSEUDOMONIC ACIDS

Enantiospecific syntheses of 1S,6S-3,7-dioxabicyclonon-4-en-8-one (1) and of the enantiomer (2) from D- and L-arabinose respectively have been achieved by two different routes.The conversion of (1) to 6S-(3R-acetanilido)-3,6-dihydro-2H-pyranyl-N,N-dimethylacetamide (3), a key intermediate in the synthesis of pseudomonic acids, is described.