85633-84-7

Basic information

• Product Name: 3-(1-Acetoxycyclohexyl)-2-methylpropannitril
• Synonyms: 3-(1-Acetoxycyclohexyl)-2-methylpropannitril
• CAS NO: 85633-84-7
• Molecular Weight: 209.288
• Mol File: 85633-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(1-Acetoxycyclohexyl)-2-methylpropannitril(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(1-Acetoxycyclohexyl)-2-methylpropannitril(85633-84-7)
• EPA Substance Registry System: 3-(1-Acetoxycyclohexyl)-2-methylpropannitril(85633-84-7)

Safety Data

• Hazardous Substances Data: 85633-84-7(Hazardous Substances Data)

Upstream product

• 80484-15-7 1-Acetoxycyclohexyl-quecksilberchlorid 
• 126-98-7 methacrylonitrile 

Relevant articles and documents

Reactions with Umpolung via Radicals: CC-Bond Formation between Ketones and Alkenes

The hydrazones 1 - 11 from ketones react in a general synthetic procedure with alkenes 33a - m to yield products 34 - 44 (table 2 and 3).Important intermediates of these reactions with umpolung are 1-acetoxyalkyl radicals 49 that are formed from organomercuric salts 14 - 24 by reduction with NaBH4.This new CC-bond formation reaction can be carried out in a one-pot synthesis without isolation of the metalorganic compounds (table 4). - In side reactions the reduction products 50 are formed, if bulky starting compounds or less reactive alkenes are used (table 5 and 6).