856409-34-2

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 856409-26-2 (1R,2R,3S,5R)-3-Azido-6,8-dioxa-bicyclo[3.2.1]octan-2-ol 
• 856409-33-1 1,6-anhydro-2-deoxy-3-O-mesyl-4-O-tosyl-β-D-arabino-hexopyranose 
• 270088-60-3 1,6-anhydro-2-deoxy-4-O-(p-toluenesulfonyl)-β-D-glucopyranose 
• 3868-08-4 1,6:2,3-dianhydro-4-O-(4-toluenesulfonyl)-β-D-mannopyranose 
• 50767-53-8 1,6:3,4-dianhydro-2-deoxy-β-D-lyxo-hexopyranose 

Relevant academic research and scientific papers

Synthesis of 1,6-anhydro-2,3,4-trideoxy-2,3-epimino- and 1,6-anhydro-2,3,4-trideoxy-3,4-epimino-β-D-hexopyranoses and their NMR and infrared spectra

A complete series of 2,3,4-trideoxy-2,3-epimino and 2,3,4-trideoxy-3,4- epimino derivatives of 1,6-anhydro-β-D-hexopyranoses were prepared by lithium aluminium hydride reduction of vicinal trans azido tosylates. Unusual formation of the aziridine ring from precursors with the trans-diequatorial arrangement of the reacting groups was observed. NMR and infrared spectra of the aziridines are discussed.