270088-60-3Relevant articles and documents
Synthesis of 1,6-anhydro-2,3,4-trideoxy-2,3-epimino- and 1,6-anhydro-2,3,4-trideoxy-3,4-epimino-β-D-hexopyranoses and their NMR and infrared spectra
Karban, Jindrich,Budesinsky, Milos,Kroutil, Jiri
, p. 1939 - 1954 (2007/10/03)
A complete series of 2,3,4-trideoxy-2,3-epimino and 2,3,4-trideoxy-3,4- epimino derivatives of 1,6-anhydro-β-D-hexopyranoses were prepared by lithium aluminium hydride reduction of vicinal trans azido tosylates. Unusual formation of the aziridine ring from precursors with the trans-diequatorial arrangement of the reacting groups was observed. NMR and infrared spectra of the aziridines are discussed.