85653-72-1Relevant academic research and scientific papers
REACTION BETWEEN Δ2-OXAZOLIN-5-ONES AND NITROSOBENZENE. FORMATION OF 1,2,4-OXADIAZOLINES
Rodriguez, H.,Pavez, H.,Marquez, A.,Navarrete, P.
, p. 23 - 27 (2007/10/02)
2,4-diphenyl- and 2-p-methylphenyl-4-phenyl-Δ2-oxazolin-5-ones react at 80-110 deg C with nitrosobenzene to give benzamidines.However, reactions conducted at room temperature afford in high yield, the heretofore undescribed Δ4-oxadiazolin-3-carboxylic acids by regiospecific 1,3-dipolar cycloaddition.Thermal decomposition of the oxadiazolinecarboxylic acids gives the corresponding benzamidines.
