85658-62-4Relevant academic research and scientific papers
Azaindole Derivatives. 63. Effect of the Solvating Capacities of Solvents on the Pathways of Reactions under the Conditions of the Hofmann Rearrangement
Bychikhina, N. N.,Azimov, V. A.,Yakhontov, L. N.
, p. 52 - 56 (2007/10/02)
It is shown that 1-benzyl-6-chloro-7-carbamoyl-5-azaindoline undergoes primarily normal skeletal rearrangement to give 1-benzyl-6-chloro-7-methoxycarbonylamino-5-azaindoline under the conditions of the Hofmann reaction in the presence of pyridine, whereas
