85662-51-7

Basic information

• Product Name: (rac)-3-phenyl-3-methylcyclopentanone
• Synonyms: (rac)-3-phenyl-3-methylcyclopentanone
• CAS NO: 85662-51-7
• Molecular Weight: 174.243
• Mol File: 85662-51-7.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: (rac)-3-phenyl-3-methylcyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: (rac)-3-phenyl-3-methylcyclopentanone(85662-51-7)
• EPA Substance Registry System: (rac)-3-phenyl-3-methylcyclopentanone(85662-51-7)

Safety Data

• Hazardous Substances Data: 85662-51-7(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 151990-53-3 3-methyl-3-phenylcyclobutan-1-one 
• 101-41-7 benzeneacetic acid methyl ester 
• 2758-18-1 3-Methyl-2-cyclopenten-1-one 
• 98-80-6 phenylboronic acid 
• 75750-06-0 2-phenyl-2-methylcyclobutanone 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 618-41-7 Benzenesulfinic acid 
• 446879-33-0 (R)-2-Methyl-5-oxo-2-phenyl-cyclopentanecarboxylic acid methyl ester 
• 13197-81-4 dimethyl(phenyl)aluminum 
• 446879-32-9 (R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide 
• 446879-31-8 (R)-methyl 2-diazo-3-oxo-6-phenylheptanoate 
• 446879-30-7 (R)-methyl 3-oxo-6-phenylheptanoate 
• 446879-29-4 (S)-(2-iodo-1-methylethyl)benzene 

Downstream Products

• 1401075-96-4 (1S,3R)-3-methyl-3-phenylcyclopentanaminium chloride 
• 1401075-93-1 (S)-2-methyl-N-((1R,3R)-3-methyl-3-phenylcyclopentyl)propane-2-sulfinamide 
• 1401075-91-9 (S)-2-methyl-N-((S,3R)-3-methyl-3-phenylcyclopentyl)propane-2-sulfinamide 
• 131726-64-2 (S)-methyl 3-oxo-1-phenylcyclopentanecarboxylate 
• 33026-43-6 2,2,3-Trimethyl-3-phenylcyclopentanon 
• 69849-76-9 3,5-Dimethyl-3-phenylcyclopentanon 
• 65564-94-5 3-Methyl-3-p-nitrophenylcyclopentanon 
• 36920-29-3 4-methyl-4-phenylcyclopent-2-en-1-one 
• 131700-53-3 (+)-2-benzylidene-4-methyl-4-phenylcyclopentanone 

Relevant articles and documents

Preparation of (S)-tert-butylpyox and palladium-catalyzed asymmetric conjugate addition of arylboronic acids

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Stepwise approach for sterically hindered Csp3-Csp3 bond formation by dehydrogenative: O -alkylation and Lewis acid-catalyzed [1,3]-rearrangement towards the arylalkylcyclopentane skeleton of sesquiterpenes

A stepwise dehydrogenative cross-coupling method was developed for the formation of sterically hindered Csp3-Csp3 bonds. Intramolecular dehydrogenative O-alkylation of a β-ketoester by 2,3-dichloro-5,6-dicyano-p-benzoquinone to form an oxolane followed by Lewis acid-catalyzed [1,3]-rearrangement furnished the sesquiterpene arylmethylcyclopentane skeleton. The formal syntheses of herbertane-type β-herbertenol, cuparane-type enokipodins A and B were also achieved.

A Pd(II)-Functionalized Covalent Organic Framework for Catalytic Conjugate Additions of Arylboronic Acids to β,β-Disubstituted Enones

A palladium(II)-functionalized covalent organic framework (Pd@TpBpy COF) constructed from 1,3,5-triformylphloroglucinol (Tp) and [2,2′-bipyridine]-5,5′-diamine (Bpy) is reported as a recyclable catalyst for conjugate additions in aqueous media. Additions