85665-21-0

Basic information

• Product Name: (-)-cis-bicyclo<3.3.0>oct-7-en-endo-2-yl (1-phenylethyl)carbamate
• CAS NO: 85665-21-0
• Molecular Weight: 271.359
• Mol File: 85665-21-0.mol

Chemical Properties

• CAS DataBase Reference: (-)-cis-bicyclo<3.3.0>oct-7-en-endo-2-yl (1-phenylethyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-cis-bicyclo<3.3.0>oct-7-en-endo-2-yl (1-phenylethyl)carbamate(85665-21-0)
• EPA Substance Registry System: (-)-cis-bicyclo<3.3.0>oct-7-en-endo-2-yl (1-phenylethyl)carbamate(85665-21-0)

Safety Data

• Hazardous Substances Data: 85665-21-0(Hazardous Substances Data)

Upstream product

• 14649-03-7 (-)-(S)-(α-methylbenzyl)isocyanate 
• 68317-62-4 bicyclo[3.3.0]oct-7-en-endo-2-ol 

Relevant articles and documents

Resolution and Absolute Configuration of Bicycloocta-2,6-diene-2-carboxylic Acid

An efficient resolution of the title acid (1) by using (+)- and (-)-α-phenethylamine is described.The (+) acid was determined to be 1S by chemical correlation through (+)-cis-bicyclooctan-2-one (3) with (+)-cis-bicyclooct-7-en-endo-2-ol (4) where the absolute configuration is known to be 1R.The 1R configuration for (-)-3 was consistent with the negative Cotton effect observed for this ketone.