85669-73-4Relevant academic research and scientific papers
PALLADIUM(0)-CATALYZED ALLYLIC ALKYLATION AND AMINATION OF ALLYLIC PHOSPHATES
Tanigawa, Yoshio,Nishimura, Kazuaki,Kawasaki, Akihiko,Murahashi, Shun-Ichi
, p. 5549 - 5552 (1982)
Allyl diethyl phosphates (1) can be easily substituted with malonates and amines in the presence of palladium(0) catalyst.Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate (1b) with high regio- and stereoselectivity.
