Tetrahedron Letters p. 5549 - 5552 (1982)
Update date:2022-08-03
Topics:
Tanigawa, Yoshio
Nishimura, Kazuaki
Kawasaki, Akihiko
Murahashi, Shun-Ichi
Allyl diethyl phosphates (1) can be easily substituted with malonates and amines in the presence of palladium(0) catalyst.Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate (1b) with high regio- and stereoselectivity.
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Doi:10.1016/0031-9422(86)80021-8
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(1947)Doi:10.1007/BF00506429
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(2005)Doi:10.1016/S0022-328X(00)98635-2
(1983)Doi:10.1039/jr9310002388
(1931)
