PALLADIUM(0)-CATALYZED ALLYLIC ALKYLATION AND AMINATION OF ALLYLIC PHOSPHATES

DOI: 10.1016/S0040-4039(00)85891-8

Source and publish data:

Tetrahedron Letters p. 5549 - 5552 (1982)

Update date:2022-08-03

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Authors:

Tanigawa, Yoshio

Nishimura, Kazuaki

Kawasaki, Akihiko

Murahashi, Shun-Ichi

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Article abstract of DOI:10.1016/S0040-4039(00)85891-8

Allyl diethyl phosphates (1) can be easily substituted with malonates and amines in the presence of palladium(0) catalyst.Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate (1b) with high regio- and stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)85891-8

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