85684-70-4Relevant academic research and scientific papers
REACTION OF p-CHLOROBENZENESULFENYL CHLORIDE WITH QUADRICYCLENE
Sadovaya, N. K.,Velikokhat'ko, T. N.,Zefirov, N. S.
, p. 217 - 220 (2007/10/02)
The reactions of quadricyclene with p-chlorobenzene- and p-toluenesulfenyl chlorides in methylene chloride were investigated.The reaction of quadricyclene with p-chlorobenzenesulfenyl chloride was studied in media with various polarities.It was shown that the nature of the initial addition products agrees with the previously proposed ion-pair reaction mechanism.When the reaction was realized in acetic acid, the reaction of the initial compounds with the solvent was a competing process.In the absence of lithium perchlorate this reaction became the main process.
