85685-28-5Relevant academic research and scientific papers
REACTION OF DIFLUOROCARBENE WITH SMALL BICYCLIC MOLECULES
Jackson, E. James,Misslitz, Ulf,Jones, Maitland,Meijere, A. de
, p. 653 - 662 (2007/10/02)
Difluorocarbene reacts with 1,2,2-trimethylbicyclobutane to give the product of two bond cleavage, 1,1-difluoro-3,3,4-trimethyl-1,4-pentadiene in 3percent yield.Bicyclopentane is even less reactive, yielding 1,1-difluorohexa-1,5-diene in ca. 0.5percent yield.Bicyclohexane does not react with difluorocarbene.Theoretical descriptions of these reactions are discussed.
REACTION OF CARBENES WITH BICYCLOPENTANE
Shiue, Gong-Huey,Misslitz, Ulf,Ding, Xin-teng,Jones, Maitland,Meijere, Armin de
, p. 5399 - 5402 (2007/10/02)
Bicyclopentane reacts with phenylcarbene and dicarbomethoxycarbene by simple insertion at the cyclobutane methylene position.By contrast, difluorocarbene reacts by two bond cleavage to give 1,1-difluoro-1,5-hexadiene.
