856900-01-1

Upstream product

• 856899-97-3 2-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-phenyl)-propionic acid methyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 127852-64-6 (S)-3-(4-methoxyphenyl)-1,2-propandiol 
• 51410-45-8 estragole oxide 
• 20401-88-1 3-(4-methoxyphenyl)propional 
• 127742-93-2 (S)-2-(4-methoxybenzyl)oxirane 

Downstream Products

• 856900-00-0 Toluene-4-sulfonic acid (S)-1-hydroxymethyl-2-(4-methoxy-phenyl)-ethyl ester 
• 220736-25-4 (4R,5S)-5-(hydroxymethyl)-4-(4-methoxyphenyl)-1,3-oxazolidin-2-one 
• 922728-73-2 (4R,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(4-methoxy-phenyl)-oxazolidin-2-one 

Relevant academic research and scientific papers

Enantioselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone via Rh-catalyzed diastereoselective oxidative C-H aminations

An efficient enantioselective synthesis of (-)-cytoxazone (1) and (+)-epi-cytoxazone (2) using proline-catalyzed asymmetric α-amino-oxylation of aldehydes followed by Rh-catalyzed diastereoselective oxidative C-H amination as the key steps is described. s

Unusual migrations and cyclization in the preparation of β-azido alcohols from β-hydroxy esters

Migration of TBDMS and Boc groups from 2° alcohols to 1° alcohols during the reduction of β-hydroxy esters has been observed. Also, unusual cyclization has been noticed during tosylation of benzylic alcohol in tert-butyl ((2R)-2-hydroxy-2-phenyl ethyl)car