85695-29-0Relevant academic research and scientific papers
Process for preparing (2,2,2-trihalo-1, 1-dihydrocarbyl-ethoxy) trihydrocarbylsilanes
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, (2008/06/13)
A process for forming trihalomethylsiloxanes by contacting a trihalosilane with a carbonyl in the presence of the fluoride ion. These compounds are used to form α-substituted acid chlorides.
TRIMETHYLSILYL TRICHLOROACETATE: A NEW REAGENT FOR SALT-FREE SILYLATIONS
Renga, James M.,Pen-Chung, Wang
, p. 1175 - 1178 (2007/10/02)
Trimethylsylil trichloroacetate (1) is a convenient reagent for the silylation of phenols, carboxylic acids, mercaptans, amides, acetylenes, and β-keto esters, while the reaction of 1 with aldehydes and ketones affords silylated trichloromethyl carbinols (5).
