85695-31-4Relevant academic research and scientific papers
TRIMETHYLSILYL TRICHLOROACETATE: A NEW REAGENT FOR SALT-FREE SILYLATIONS
Renga, James M.,Pen-Chung, Wang
, p. 1175 - 1178 (1985)
Trimethylsylil trichloroacetate (1) is a convenient reagent for the silylation of phenols, carboxylic acids, mercaptans, amides, acetylenes, and β-keto esters, while the reaction of 1 with aldehydes and ketones affords silylated trichloromethyl carbinols (5).
TRICHLOROMETHYL ANION CHEMISTRY FROM TRIMETHYLSILYL TRICHLOROACETATE
Jesus, Miguel A. de,Prieto, J. Antonio,Valle, Luis del,Larson, Gerald L.
, p. 1047 - 1052 (2007/10/02)
The reaction of trimethylsilyl trichloroacetate with aldehydes and ketones in the presence of fluoride ion gives the trichloromethyl adducts.With potassium fluoride the reaction with cyclohexenone and crotonaldehyde results in clear 1,2 addition.
