85695-63-2Relevant academic research and scientific papers
A NOVEL METHOD FOR PREPARATION OF 2-(METHYL- OR PHENYLTHIO)ALKANOIC ESTERS
Ogura, Katsuyuki,Sanada, Kunio,Takahashi, Kazumasa,Iida, Hirotada
, p. 4035 - 4038 (2007/10/02)
Ethyl 2-acetylalkanoate gave ethyl 2-(methyl- or phenylthio)alkanoate in high yield on treatment with CH3SSO2CH3, PhSSO2Ph, or PhSSPh in the presence of small excess of EtONa in EtOH.Application of the present method to synthesis of pellitorine and thr queen substance is also described.
