85696-92-0

Basic information

• Product Name: 6-Thiabicyclo[3.2.1]octane-1-carboxylic acid, 4-hydroxy-4-methyl-8-oxo-, methyl ester
• CAS NO: 85696-92-0
• Molecular Formula: C10H14O4S
• Mol File: 85696-92-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-Thiabicyclo[3.2.1]octane-1-carboxylic acid, 4-hydroxy-4-methyl-8-oxo-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Thiabicyclo[3.2.1]octane-1-carboxylic acid, 4-hydroxy-4-methyl-8-oxo-, methyl ester(85696-92-0)
• EPA Substance Registry System: 6-Thiabicyclo[3.2.1]octane-1-carboxylic acid, 4-hydroxy-4-methyl-8-oxo-, methyl ester(85696-92-0)

Safety Data

• Hazardous Substances Data: 85696-92-0(Hazardous Substances Data)

Upstream product

• 2689-68-1 methyl 4-oxotetrahydrothiophene-3-carboxylate 
• 85696-91-9 methyl 4-oxo-3-(3-oxobutyl)tetrahydrothiophene-3-carboxylate 
• 78-94-4 methyl vinyl ketone 

Relevant articles and documents

The Acid-catalysed Cyclisation of Methyl 1-(3-Oxobutyl)-2-oxocyclopentanecarboxylate: X-Ray Analysis of the Product

An X-ray analysis confirm that the acid-catalysed cyclisation of methyl 1-(3-oxobutyl)-2-oxocyclopentanecarboxylate leads to the formation of methyl 5-methyl-7-oxo-6-oxabicyclononane-1-carboxylate via a rearrangement reaction.

Methyl 4-Oxothiolane-3-carboxylate and Methyl 2-Methyl-4-oxothiolane-3-carboxylate Anions as Synthetic Equivalents of α-Acrylate and α-Crotonate Anions. Formal Synthesis of Integerrinecic Acid

The base-promoted fragmentation of the C-alkylation products (6a-h) and (8a-e) of methyl 4-oxothiolane-3-carboxylate (4) and methyl 2-methyl-4-oxothiolane-3-carboxylate (5) gave good yields of the α-substituted acrylates (7a-h) and α-substituted crotonate