85698-68-6

Basic information

• Product Name: Phenyl<1-(trimethylsilyl)ethenyl>tellurid
• Synonyms: Phenyl<1-(trimethylsilyl)ethenyl>tellurid
• CAS NO: 85698-68-6
• Molecular Weight: 303.934
• Mol File: 85698-68-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenyl<1-(trimethylsilyl)ethenyl>tellurid(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl<1-(trimethylsilyl)ethenyl>tellurid(85698-68-6)
• EPA Substance Registry System: Phenyl<1-(trimethylsilyl)ethenyl>tellurid(85698-68-6)

Safety Data

• Hazardous Substances Data: 85698-68-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 85698-66-4 1-lithio-1-(phenyltelluro)ethene 

Relevant articles and documents

New Reagents, XXVI. (Phenyltelluro)ethene, 1-Lithio-1-(phenyltelluro)ethene, and (Phenyltelluro)ethyne, Synthesis and Reactions

(Phenyltelluro)ethene (2a, 78percent) and -ethyne (4, 51percent) were synthesized for the first time.By lithiation with bulky lithium amides (lithium 2,2,6,6-tetramethylpiperidide and lithium dicyclohexylamide) 1-lithio-1-(phenyltelluro)ethene (2b) was obtained from 2a (ca. 50percent yield). 2b reacts with benzaldehyde and chlorotrimethylsilane to give the expected products 2c (88percent) and 2e (80percent), respectively, but no reaction occurred with 1-iodopropane and allyl bromide.