85707-11-5Relevant academic research and scientific papers
STREOSELECTIVE REDUCTION OF THE STEROIDAL 23-EN-22-ONE: A ROUTE TO THE SIDE CHAIN OF THE PLANT GROWTH PROMOTER BRASSINOLIDE.
Takahashi, Takashi,Ootake, Atsushi,Yamada, Haruo,Tsuji, Jiro
, p. 69 - 72 (1985)
The side chain of brassinolide (1) was streoselectively synthesized, in which the 20(S)- and the 22(R)-configurations were introduced by the alkylation (SN2) of the 20(R)-tosyloxy steroid 7 with the protected cyanohydrin 8 followed by the streo
