85716-64-9Relevant academic research and scientific papers
KINETICALLY CONTROLLED NUCLEOPHILIC ADDITION-REACTIONS TO METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-NITRO-α-D-erythro-HEX-2-ENOPYRANOSIDE
Sakakibara, Tohru,Tachimori, Yoshofusa,Sudoh, Rokuro
, p. 197 - 208 (2007/10/02)
Axial attack mainly occured in the reactions of methyl 4,6-O-benzylidene-2,3-dideoxy-2-nitro-α-D-erythro-hex-2-enopyranoside with sodium borodeuteride, hydrogen peroxide, hydrogen cyanide, and methanol, whereas equatorial attack predominated in the reacti
STEREOSELECTIVE NUCHLEOPHILIC ADDITION REACTIONS TO NITRO SUGARS
Sakakibara, Tohru,Tachimori, Yoshifusa,Sudoh, Rokuro
, p. 5545 - 5548 (2007/10/02)
Nucleophile(s) almost exclusively added from the equatorial side of 2-nitro-β-D-2-enopyranoside and the axial side of 2-nitro-D-ribo-1-enitol.On the other hand, methoxide and tert-butyl peroxide ions approached from the equatorial side of 2-nitro-α-D-2-en
