857592-35-9Relevant academic research and scientific papers
UNUSUAL DEALKYLATIONS AND REARRANGEMENTS IN AROMATIC NUCLEOPHILIC SUBSTITUTION
Nudelman, N. Sbarbati,Socolovsky, S. E.
, p. 3331 - 3334 (1980)
The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product.Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine.A carbanionic mechanism is proposed.
