Tetrahedron Letters p. 3331 - 3334 (1980)
Update date:2022-07-30
Topics:
Nudelman, N. Sbarbati
Socolovsky, S. E.
The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product.Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine.A carbanionic mechanism is proposed.
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