85808-13-5Relevant academic research and scientific papers
Preparation of the First Organoselenium Peroxide, t-Butyl Benzeneperoxyseleninate
Bloodworth, A. J.,Lapham, David J.
, p. 471 - 474 (2007/10/02)
t-Butyl benzeneperoxyseleninate, PhSe(O)OOBut, has been prepared by the reaction of t-butyl hydroperoxide with PhSe(O)OSe(O)Ph or PhS(O)OEt, and of sodium t-butyl peroxide with PhSe(O)Br.Formation of the less stable analogues p-MeC6H4Se(O)OOBut and BuSe(O)OOBut from t-butyl hydroperoxide and the corresponding seleninyl anhydrides has been confirmed by 13C n.m.r. spectroscopy.
