85808-21-5

Upstream product

• 26706-86-5 5-methyl-2-oxo-cyclohexanecarbaldehyde 
• 931-59-9 benzenesulfenyl chloride 
• 589-92-4 1-methylcyclohexan-4-one 
• 85808-19-1 2-Diazo-4-methyl-cyclohexanone 

Relevant academic research and scientific papers

REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)CYCLOALKENONES AND OF α-PHENYL-α-(PHENYLTHIO)KETONES VIA αα-ADDITION OF PHENYLSULPHENYL CHLORIDE TO α-DIAZOKETONES

Cyclic α-diazoketones react with phenylsulphenyl chloride at room temperature to furnish α-chloro-α-(phenylthio)cycloalkanones which undergo ready dehydrochlorination to α-(phenylthio)cycloalkenones when treated with triethylamine; acyclic, terminal α-diazoketones also furnish α-chloro-α-(phenylthio)adducts which are useful electrophiles in the synthesis of α-phenyl-α-(phenylthio)ketones.