858129-50-7Relevant academic research and scientific papers
Asymmetric synthesis of α-substituted β-amino ketones from sulfinimines (N-sulfinyl imines). Synthesis of the indolizidine alkaloid (-)-223A
Davis, Franklin A.,Yang, Bin
, p. 8398 - 8407 (2007/10/03)
Of the possible four stereoisomers, addition of the lithium enolate of 4-heptanone to sulfinimines resulted in only the syn- and anti-α- substituted β-amino ketones. The formation of the major syn-β-amino ketone was rationalized in terms of addition of th
