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85826-52-4

2H-Pyrrol-2-ol, 3,4-dihydro-4,4-dimethyl-5-phenyl- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 85826-52-4 Structure

  • Basic information

    1. Product Name: 2H-Pyrrol-2-ol, 3,4-dihydro-4,4-dimethyl-5-phenyl-
    2. Synonyms:
    3. CAS NO:85826-52-4
    4. Molecular Formula: C12H15NO
    5. Molecular Weight: 189.257
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 85826-52-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2H-Pyrrol-2-ol, 3,4-dihydro-4,4-dimethyl-5-phenyl-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2H-Pyrrol-2-ol, 3,4-dihydro-4,4-dimethyl-5-phenyl-(85826-52-4)
    11. EPA Substance Registry System: 2H-Pyrrol-2-ol, 3,4-dihydro-4,4-dimethyl-5-phenyl-(85826-52-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 85826-52-4(Hazardous Substances Data)

85826-52-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 85826-52-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,8,2 and 6 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 85826-52:
(7*8)+(6*5)+(5*8)+(4*2)+(3*6)+(2*5)+(1*2)=164
164 % 10 = 4
So 85826-52-4 is a valid CAS Registry Number.

85826-52-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,4-dimethyl-5-phenyl-2,3-dihydropyrrol-2-ol

1.2 Other means of identification

Product number -
Other names 2H-Pyrrol-2-ol,3,4-dihydro-4,4-dimethyl-5-phenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:85826-52-4 SDS

85826-52-4Relevant articles and documents

Synthesis of 5-hydroxy-Δ1-pyrrolines from sec-alkyl aryl ketoximes and acetylene

Shabalin, Dmitrii A.,Dvorko, Marina Yu.,Schmidt, Elena Yu.,Ushakov, Igor’ A.,Trofimov, Boris A.

, p. 6661 - 6667 (2016)

Synthesis of 5-hydroxy-Δ1-pyrrolines conjugated with aryl substituents has been effected via the rearrangement of O-vinylketoximes, having only one C–H bond adjacent to the oxime function and readily prepared by addition of sec-alkyl aryl ketox

Metal-Free Selective Synthesis of 1,4-Dihydropyridazines from Hydroxypyrrolines and Hydrazines

Shabalin, Dmitrii A.,Dvorko, Marina Yu.,Zolotareva, Evgeniya E.,Ushakov, Igor' A.,Vashchenko, Alexander V.,Schmidt, Elena Yu.,Trofimov, Boris A.

, p. 4004 - 4010 (2017)

An efficient and selective synthesis of 1,4-dihydropyridazines through the acid-catalyzed recyclization of 5-hydroxy-Δ1-pyrrolines with hydrazines has been developed. The scope of this reaction was thoroughly explored, resulting in the generation of a library of 1,4-dihydropyridazines in good to excellent yields (25 examples, 67–100 % yields).

Synthesis of 5-hydroxy-Δ1-pyrrolines from aryl isoalkyl ketoximes and acetylene in a tuned superbase medium

Shabalin, Dmitrii A.,Dvorko, Marina Yu.,Schmidt, Elena Yu.,Protsuk, Nadezhda I.,Trofimov, Boris A.

supporting information, p. 3156 - 3159 (2016/07/06)

The reaction between aryl isoalkyl ketoximes and acetylene under atmospheric pressure was applied to the synthesis of 5-hydroxy-Δ1-pyrrolines, containing aromatic substituents at the carbon–nitrogen double bond, in moderate yields. A crucial fa

Synthesis of 3,3-dimethyl-2-phenyl-3H-pyrrole from Isopropyl Phenyl Ketoxime and Acetylene: A Side Formation of 4,4-dimethyl-5-phenyl-1-vinyl-2- pyrrolidinone as Clue to the Reaction Mechanism

Shabalin, Dmitrii A.,Glotova, Tatyana E.,Schmidt, Elena Yu.,Ushakov, Igor A.,Mikhaleva, Al'Bina I.,Trofimov, Boris A.

, p. 100 - 101 (2014/04/17)

Isopropyl phenyl ketoxime reacts with acetylene in the KOH/DMSO suspension (atmospheric pressure, 90 °C, 4 h) to afford 3,3-dimethyl-2-phenyl-3H- pyrrole (30%) and 4,4-dimethyl-5-phenyl-1-vinyl-2-pyrrolidinone (5%) that is likely originated from 4,4-dimethyl-5-phenyl-3,4-dihydro-2H-pyrrol-2-ol as the key reaction intermediate.

A NOVEL SYNTHESIS OF 3H-PYRROLES

Korostova, S. E.,Shevchenko, S. G.,Sigalov, M. V.

, p. 1101 - 1104 (2007/10/02)

Reaction of isopropylphenyl- and isopropyl-2-thienylketoximes with acetylene, catalyzed by the system MOH (M = Na, K)-DMSO, gave 2-phenyl- and 2-(2-thienyl)-3,3-dimethyl-3H-pyrroles as well as the reaction intermediates O-vinylisopropylphenylketoxime and

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