85827-41-4

Basic information

• Product Name: trans-4-fluorophenylbis(triphenylphosphine)platinum chloride
• CAS NO: 85827-41-4
• Molecular Weight: 850.211
• Mol File: 85827-41-4.mol

Chemical Properties

• CAS DataBase Reference: trans-4-fluorophenylbis(triphenylphosphine)platinum chloride(CAS DataBase Reference)
• NIST Chemistry Reference: trans-4-fluorophenylbis(triphenylphosphine)platinum chloride(85827-41-4)
• EPA Substance Registry System: trans-4-fluorophenylbis(triphenylphosphine)platinum chloride(85827-41-4)

Safety Data

• Hazardous Substances Data: 85827-41-4(Hazardous Substances Data)

Upstream product

• 14221-02-4 tetrakis(triphenylphosphine)platinum 
• 589-20-8 HgCl(p-FC₆H₄) 

Downstream Products

• 103903-76-0 trans-4-fluorophenylbis(triphenylphosphine)platinum thiophenoxide 

Relevant articles and documents

REDOX-DEMERCURATION OF PHENYLMERCURY 4-FLUOROTHIOPHENOXIDE BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

A method for the synthesis of organoplatinum compounds containing a Pt-S ?-bond has been found.PhPt(PPh3)2SC6H4F-4 and 4-FC6H4Pt(PPh3)2SPh was obtained by redox-demercuration of PhHgSC6H4F-4 under the action of Pt(PPh3)4.

On the Reductive Elimination of the Biphenyl System from Substituted cis-Bis(phenyl)bis(triphenylphosphane)platinum(II) Compounds

The compounds cis- and cis- have been synthesized and studied thermally with respect to the reductive elimination of disubstituted biphenyls.Activation parameters ΔH and ΔS are reported and discussed. - Keywords: Platinum-organic Compounds, Syntheses, Reductive Elimination, Activation Parameters